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Industrial Hemp Fibers: An Overview



                                                  1              1                   2
                                    João P. Manaia ,*, Ana T. Manaia  and Lúcia Rodriges
                                     1
                                       Laboratory for Wear, Testing & Materials (LED&MAT),
                  Instituto Pedro Nunes, Rua Pedro Nunes, 3030-199 Coimbra, Portugal; Email: [email protected]
                                          2
                                            CITEVE, Rua Fernando Mesquita, 2785,
                             4760-034 Vila Nova de Famalicão, Portugal; Email: [email protected]
                      * Correspondence: [email protected] or [email protected]; Tel.: +351-963-128-954

                 Abstract: Industrial hemp (Cannabis sativa) is one of the most available and widely produced bast
                 fibers with high cellulose content. Interest in these fibers is warranted due to environmental protection
                 challenges as well as their inherent properties such as low density, high specific strength, and stiffness.
                 In addition, advanced research and progress have gone into increasing their mechanical performance
                 through surface treatments and in the development of new materials. The most promising application for
                 hemp fibers is as reinforcement in polymeric composites or through hybridization.

                 Nonetheless, more research is needed to improve their properties and expand their range of applica-
                 tions. The biodegradability issue is one problem that must be addressed when considering long life-
                 cycle applications as the reproducibility of these composites’ final properties. This review is a compre-
                 hensive literature review on hemp fibers. It includes hemp fibers’ chemical and mechanical properties,
                 surface modifications, hybrid composites, as well as current and future applications.
                 Keywords: hemp fibers; surface treatments; hybrid composites; mechanical properties; industrial appli-
                 cations

                                            Joshi et al. [12] compared the life-cy-  bers are their inherited hydrophilic char-
                    Introduction
                                            cle assessment of three components  acter, highly anisotropic nature, low re-
                                            made from natural fiber-reinforced  sistance to microorganisms, low ther-
         Environmental protection is one of the
                                            composites and glass fiber-reinforced  mal stability, variation in mechanical
         greatest challenges facing the current
                                            composites. They found that natural  properties, and mechanical properties
         generation [1]. Due to increasing envi-
                                            fiber-reinforced composites emerged  lower than those of synthetic fibers [6].
         ronmental concern and protection, the
                                            more environmentally friendly, mainly  Additionally, it is recognized that vari-
         number of available studies dealing
                                            for three reasons: (1) natural fiber pro-  ous aspects such as growth condition,
         with the potential use of natural fibers
                                            duction had the lower environmental  harvesting methods, and maturity of-
         in developing thermoset and thermo-
                                            impacts, (2) natural fiber composites  ten affect natural fiber properties [11].
         plastics composites as well as improv-
                                            had higher fiber content for equivalent
         ing their mechanical performance                                      The hydrophilic character of natural fi-
                                            performance, which reduced the vol-
         through physical and chemical surface                                 bers results in poor interfacial interac-
                                            ume and weight of the base polymeric
         treatments is growing.                                                tion between the matrix and fiber and
                                            matrix, and (3) the lower weight of the
                                                                               poor fiber dispersion, as well as high
         Furthermore, natural fibers are getting  resultant components reduced the
                                                                               moisture absorption, which might lead
         more attention as possible alternative  emissions and fuel consumption in its
                                                                               to fiber swelling and debonding of the
         replacements for synthetic fibers, such  life cycle.
                                                                               matrix-fiber interface [14,15].  The
         as glass fibers [2–7].
                                            The life-cycle assessment, performed  moisture absorption in natural fiber-re-
         Natural fibers are eco-friendly [8], are  by La Rosa et al. [13], showed that  inforced composites is governed by
         non-abrasive to the processing equip-  hemp mats in glass fiber-reinforced  three different diffusion mechanisms,
         ment, are relatively low cost, are from  thermoset composites are more envi-  namely, (1) water diffusion between the
         renewable resources, have low densi-  ronmentally friendly than the conven-  polymer microcaps, (2) capillary trans-
         ty, and have high specific strength and  tional single use of glass fiber, due to  ports into flaws and defects at the
         stiffness [8,9].                   the reduction of glass fiber and resin  matrix-fiber interface, and (3) transpor-
                                            content.                           tation through microcracks formed dur-
         On average, natural fiber production
                                                                               ing the fiber’s swelling process [16].
         uses 60% less energy than glass fiber
                                            While there are a wide number of ben-
         production, and results in lower air                                  This review article describes the re-
                                            efits in using natural fibers, there are
         emissions [10]. Moreover, the wastes                                  cent research works related to various
                                            also some disadvantages.
         are mostly organic and 100% biode-                                    aspects of hemp fibers and their use
         gradable [7,11].                   The major disadvantages of natural fi-  in the reinforcement of composites.
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