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Chitosan-Based Sustainable Textile Technology:



                        Process, Mechanism,




                       Innovation, and Safety



                         Jagadish Roy, Fabien Salaün, Stéphane Giraud, Ada Ferri and Jinping Guan
                                               http://dx.doi.org/10.5772/65259

                Abstract
                This paper reviews relevant findings regarding the activities and contributions of chitosan in different
                textile processing following the varieties of process, mechanism, and applications. Chitosan is a better
                candidate in both aspects of biodegradability and effciency instead of synthetic polymers. The technical
                and scientific discussions behind the role of chitosan in all the processes and treatments have been
                explored in the paper. Over the last few years, enormous efiorts and challenges are being practiced in
                research and industry to design and development of eco-friendly and sustainable technologies. Therefore,
                the chapter emphasizes on chitosan-based formulations of fibers, fabrics, coatings, and functional textiles.
                Keywords: chitin, chitosan, textile, fiber, fabric, antibacterial, nanofibers, electrospun

         Introduction
                                                        Table 1: Chitosan fibers and their applications.
         The first discovery of chitin was traced  Application                   System
         by Braconnot, a French professor, in
                                             Antibacterial cotton fibers         Fiber-reactive chitosan derivative
         1811 in research on the mushroom.
         Later on, Rouget discovered the     Cell culture                        Chitosan-based nanofiber
         solubility test through chemical and
                                             Biodegradable & biocompatible       Chitin and chitosan nanofibers
         thermal treatment of chitin fiber in 1859
                                             nonwoven wound dressing             [spinning solvent: 1,1,1,3,3,3-
         [1]. Ledderhose identified the chitin
                                                                                 hexafluoro-2-propanol (HFIP)]
         molecular structure, which consists of
         glucosamine and acetic acid, in 1878  Bioactive & biodegradable          Dibutyrylchitin fibers
         and Hoppe-Seyler announced the name  Wound dressing
         ‘chitosan’of the modified chitin in 1894.
                                            possesses the superior mechanical  applications (Table 1) and in the form
         Chitin is a very common bio product  property and very diverse biological  of nanofibers, membranes, micro-/
         produced naturally in the exoskeleton  activity. The chitosan-derived products  nanoparticles, scaffolds, beads,
         of crustaceans and insects (spiders,  have a slow-growing market for poor  hydrogels, and sponges.
         shrimps, crabs, and lobster), the  reproducibility in product development.  Due to the growing concern about
         radulae of mollusks and the cell wall                                 health, environment, and economics,
         of mushrooms, algae, and fungi. The  The first and second-generation  enzymatic synthesize of chitosan is
         amount of chitin produced naturally  chitosans have been used as a    continuously studied as an alternative
                        10
         each year is 10  ton of which 70%  biomaterial    and     biological  to the hazardous process and
         comes from oceans. Therefore, the by-  functionalities for wastewater treatment  nonspeciffcity  for  chitosan
         product of the fishing industry is  and agricultural applications, but the  fuctionalization. Besides, the
         enough to support the huge         scenario alters now. The third phase of  sustainability and safety in textile
         commercial demand of chitin and    chitosan exhibits strong relationship in  technology are being practiced and
         chitosan with a long-term potential  molecular structure-function. Up to  equipped by innovating new process,
         supply. The main advantages of using  date, studies and investigations are  machinery, and designs from raw
         chitosan are biodegradable [2, 3],  approaching to understand the cellular  materials to the end of life cycle.
         biocompatible [4, 5], and nontoxic  mode of action to reveal every
         because it degrades as sugar after  biological and biomedical activity of  Chemistry of chitin and chitosan
         being metabolized.                 chitosan which will open the door for
                                            new material applications. Chitin and  According to the chemical structure of
         Chitosan is a biomaterial which    chitosan have very diversified use in  chitin (Figure 1) and chitosan (Figure


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